Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.     

从第三极到北极： 积雪变化研究进展

在全球气候变化背景下， 第三极和北极地区积雪是地表最活跃的自然要素之一， 其动态变化对气候环境和人类生活产生重要影响。通过回顾第三极和北极积雪研究进展， 阐述了降雪、 积雪范围、 积雪日数、 积雪深度和雪水当量在第三极和北极地区的时空分布特征和变化趋势。结果表明： 近50年， 特别是进入21世纪以来， 第三极和北极地区降雪比率均呈下降趋势； 积雪范围、 积雪日数、 积雪深度、 雪水当量总体均呈减小趋势， 融雪首日有所提前。同时就积雪变化对生态系统与气候系统的影响进行了论述， 评估了积雪的反馈作用。通过总结第三极和北极积雪变化研究进展， 凝练研究中存在的不足和未来发展趋势， 为提升积雪对气候变化及经济社会发展影响的认识提供重要科学支撑。     

Spatial Distribution Assessment and Source Apportionment of Land-Based Pollutant Yield from Qingdao,China

The spatial distribution of chemical oxygen demand(COD) and total nitrogen(TN) yield from Qingdao are studied by comparing pollutant yield amount, densities and spatial aggregation(Getis-Ord indexes) among the land-based pollutant source regions(PSRs) entering the three sub-seas(i.e. the Jiaozhou Bay(JZB), other coastal area in the Yellow Sea(OCAYS) and Laizhou Bay(LZB), respectively). Industrial composition of the loads are also studied by comparing pollutant yield among the sources of agriculture, rural domesticity, industry, urban domesticity and service, and calculation of Gini coefficient. Results show that spatial distribution of COD and TN yield from Qingdao are extremely unbalanced. The JZB, with less than 3% of the total coastal sea area of Qingdao, received 62% COD load and 65% TN yield from Qingdao, while the OCAYS, with more than 97% area, only received 23% COD and 20% TN, which consist with the much worsen water quality of JZB than that of OCAYS. On the other hand, the source apportionment of COD and TN loads in the PSRs entering JZB and the OCAYS was similar. The agricultural and domestic sources with high pollution intensity account for more than 80%, while the industrial and service sources with low pollution intensity account for less than 20%. While Gini coefficients, COD 0.81 and TN 0.84 which are much higher than the ‘imbalance' threshold of 0.4, show the uneven industrial structure of Qingdao. These results may be useful in the determination of land-based pollution total amount control at the PSR level.     

A novel coupled FDM-DEM modelling method for flexible membrane boundary in laboratory tests

Difficulties are involved in discrete element method (DEM) modelling of the flexible boundary, that is, the membranes covering the soil sample, which can be commonly found in contemporary laboratory soil tests. In this paper, a novel method is proposed wherein the finite difference method (FDM) and DEM are coupled to simulate the rubber membrane and soil body, respectively. Numerical plane strain and triaxial tests, served by the flexible membrane, are implemented and analysed later. The effect of the membrane modulus on the measurement accuracy is considered, with analytical formulae derived to judge the significance of this effect. Based on an analysis of stress-strain responses and the grain rotation field, the mechanical performances produced by the flexible and rigid lateral boundaries are compared for the plane strain test. The results show that (1) the effect of the membrane on the test result becomes more significant at larger strain level because the membrane applies additional lateral confining pressure to the soil body; (2) the tested models reproduce typical stress and volumetric paths for specimens with shear bands; (3) for the plane strain test, the rigid lateral boundary derives a much higher peak strength and larger bulk dilatation, but a similar residual strength, compared with the flexible boundary. The latter produces a more uniform (or ‘diffuse') rotation field and more mobilised local kinematics than does the former. All simulations show that the proposed FDM-DEM coupling method is able to simulate laboratory tests with a flexible boundary membrane.     

基于ROMS和4DVAR的沿轨与网格化SSH数据同化效果评价

Remote sensing products are significant in the data assimilation of an ocean model. Considering the resolution and space coverage of different remote sensing data, two types of sea surface height(SSH) product are employed in the assimilation, including the gridded products from AVISO and the original along-track observations used in the generation. To explore their impact on the assimilation results, an experiment focus on the South China Sea(SCS) is conducted based on the Regional Ocean Modeling System(ROMS) and the four-dimensional variational data assimilation(4 DVAR) technology. The comparison with EN4 data set and Argo profile indicates that, the along-track SSH assimilation result presents to be more accurate than the gridded SSH assimilation, because some noises may have been introduced in the merging process. Moreover, the mesoscale eddy detection capability of the assimilation results is analyzed by a vector geometry–based algorithm. It is verified that, the assimilation of the gridded SSH shows superiority in describing the eddy's characteristics, since the complete structure of the ocean surface has been reconstructed by the original data merging.     

高速铁路无砟轨道地基泥岩膨胀性分类分级研究

红层泥岩是一种典型侏罗系沉积岩，其含有微量黏土矿物，易遇水软化、失水崩解，具有一定膨胀性，是引起兰新高速铁路路基持续上拱变形的一个重要因素，故重新判定该种土体膨胀性对高速铁路无砟轨道设计和施工具有重要意义。为此，选取等效蒙脱石含量、阳离子交换量、自由膨胀率和液限为泥岩膨胀性判别指标，通过兰新高速铁路上拱地段大量钻孔实测资料，提出了泥岩膨胀等级分级标准，采用改进层次分析法、基尼系数法和直觉模糊理论确定了判别指标组合权重，基于逼近理想解排序法(TOPSIS法)建立了泥岩膨胀性直觉模糊综合评价模型。结果表明：直觉模糊综合评价模型将泥岩膨胀性进行了定量化，克服了同一试样不同指标属于不同等级判别缺陷；室内膨胀量试验验证了膨胀等级分级标准和直觉模糊综合评价模型对兰新高铁地基泥岩适用性和准确性。研究成果对地基红层泥岩高速铁路路基长期持续上拱变形风险评估和工程控制措施提供技术支撑。     

全球气候变化下南海诸岛保护优先区识别分析

全球变化下,珊瑚礁保护区是保护生物多样性、增强珊瑚礁对气候变暖抵抗力的有效方式,而维持珊瑚礁弹性是其核心内容。针对珊瑚礁最具有威胁性的热压力因子,基于南海1982—2009年卫星观测海表面温度（SST）数据和CMIP5加拿大地球系统模式CanESM2模型预估的2006—2100年南海SST数据构建热压力强度模型,从维持珊瑚礁弹性的角度识别IPCC RCP 4.5和RCP 8.5情景下南海诸岛保护优先区。结果表明：RCP 4.5和RCP 8.5情景下13%左右的南海诸岛珊瑚礁识别为保护优先区。根据热压力强度与珊瑚抵抗力及避难所关系,西沙群岛七连屿和晋卿岛近年观测与未来预估的热压力强度均比较低,在保障其服务功能的基础上建议实施完全保护;东沙群岛东沙环礁和中沙环礁排洪滩近年观测急性热压力强度较高但未来预估热压力强度较低,建议实施50%禁止利用保护;中沙群岛黄岩岛近年观测和未来预估的急性热压力强度均比较低,建议实施50%多用途保护。南沙群岛有14%左右的珊瑚礁识别为保护优先区,根据其热压力强度可实施30%~100%禁止利用保护或30%~50%多用途保护。RCP 4.5和RCP 8.5情景下的南海诸岛保护优先区及保护对策,可为维持珊瑚礁生态弹性及应对全球气候变化提供重要的参考价值。     

基于GIS的石家庄市雾霾分析

为了得出雾霾气象成因机制、影响因素和时空分布特征,以石家庄市区与郊县为研究区域,将2013年9月至2016年12月石家庄市各市区、郊县的PM2.5历史监测数据中的有效数据进行了数据分析处理得到雾霾浓度数据,还有温度、降水、风速、地形和人口密度等数据,运用GIS分析的方法,模拟绘制石家庄雾霾的时空分布图、雾霾与各影响因子的专题对比图,得到雾霾形成机制的因子、雾霾的时空分布规律、雾霾季节变化特征、雾霾与地形间的关系等;运用数据分析软件OriginPro8.SR3分析雾霾浓度与风速数据、降雨数据、温度数据间的相关性。     

基于纹理和空间特征的中分辨率影像滨海水产养殖用地提取研究

近年来,水产养殖用地分布广泛,但由于其在影像上所表现的复杂性和不均匀性,造成该用地类型提取中的困难,尤其针对中分辨率遥感影像。对此,本文提出了一种基于纹理和空间特征的养殖用地提取方法,该方法主要包括3个步骤：首先,利用纹理熵和归一化差异水体指数NDWI实现水产养殖用地的粗提取;然后,依据相邻地物间的关系实现同类型地物合并;最后,本文构建一种相对宽度作为地物的近似宽度,再次利用NDWI实现水产养殖用地的准确识别。本文以越南万丰湾为研究区域,以Landat-8融合影像（融合后的像元大小为15 m）的目视解译结果为标准,对本文方法与最小距离法分类结果进行比较。实验结果表明,该方法的精度可达91.13%,远高于传统的面向对象方法,并且所提方法的错误率和虚假率分别为0.09%和8.87％,表明了该方法可靠性,因而该方法可为基于中分辨率影像的地物类型提取提供一种有效手段。